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Crystal structures of [IrCl(2)(NHCHPh)((dppm)(C(N(2)dppm))-κ(3) P,C,P′)]Cl·5.5MeCN and [IrI(NHCHPh)(((dppm)C(N(2)))-κ(2) P,C)(dppm-κ(2) P,P′)]I(I(3))·0.5I(2)·MeOH·0.5CH(2)Cl(2): triazene fragmentation in a PCN pincer iridium complex
The structure of [IrCl(2)(C(58)H(51)N(3)P(4))]Cl·5.5CH(3)CN or [IrCl(2)(NHCHPh)(((dppm)C(N(2)dppm))-κ(3)P,C,P)]Cl·5.5CH(3)CN [3, dppm = bis(diphenylphosphino)methane; systematic name: dichlorido(1,1,3,3,7,7,9,9-octaphenyl-4,5-diaza-1,3λ(5),7λ(4),9-tetraphosphanona-3,5-dien-6-yl-κ(2) P (1),P...
Autores principales: | Pauer, Bettina, Partl, Gabriel Julian, Oberparleiter, Stefan, Schuh, Walter, Kopacka, Holger, Wurst, Klaus, Peringer, Paul |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6362634/ https://www.ncbi.nlm.nih.gov/pubmed/30800447 http://dx.doi.org/10.1107/S2056989019000136 |
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