Stable salts of the hexacarbonyl chromium(I) cation and its pentacarbonyl-nitrosyl chromium(I) analogue

Homoleptic carbonyl radical cations are a textbook family of complexes hitherto unknown in the condensed phase, leaving their properties and applications fundamentally unexplored. Here we report on two stable 17-electron [Cr(CO)(6)](•+) salts that were synthesized by oxidation of Cr(CO)(6) with [NO]...

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Detalles Bibliográficos
Autores principales: Bohnenberger, Jan, Feuerstein, Wolfram, Himmel, Daniel, Daub, Michael, Breher, Frank, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6367395/
https://www.ncbi.nlm.nih.gov/pubmed/30733449
http://dx.doi.org/10.1038/s41467-019-08517-2

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6367395/
https://www.ncbi.nlm.nih.gov/pubmed/30733449
http://dx.doi.org/10.1038/s41467-019-08517-2

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