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Nickel-Catalyzed Addition of Aryl Bromides to Aldehydes To Form Hindered Secondary Alcohols

[Image: see text] Transition-metal-catalyzed addition of aryl halides across carbonyls remains poorly developed, especially for aliphatic aldehydes and hindered substrate combinations. We report here that simple nickel complexes of bipyridine and PyBox can catalyze the addition of aryl halides to bo...

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Detalles Bibliográficos
Autores principales: Garcia, Kevin J., Gilbert, Michael M., Weix, Daniel J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6368192/
https://www.ncbi.nlm.nih.gov/pubmed/30693771
http://dx.doi.org/10.1021/jacs.8b13709