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Metal-free visible light photoredox enables generation of carbyne equivalents via phosphonium ylide C–H activation
Carbyne, an interesting synthetic intermediate, has recently been generated from hypervalent iodine precursors via photoredox catalysis. Given the underexplored chemistry of carbyne, due to the paucity of carbyne sources, we are intrigued to discover a new source for this reactive species from class...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6368212/ https://www.ncbi.nlm.nih.gov/pubmed/30842832 http://dx.doi.org/10.1039/c8sc04195d |