Oxygen transfer in electrophilic epoxidation probed by (17)O NMR: differentiating between oxidants and role of spectator metal oxo

Peroxide compounds are used both in laboratory and industrial processes for the electrophilic epoxidation of olefins. Using NMR-spectroscopy, we investigate why certain peroxides engage in this type of reaction while others require activation by metal catalysts, e.g. methyltrioxorhenium (MTO). More...

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Detalles Bibliográficos
Autores principales: Ehinger, Christian, Gordon, Christopher P., Copéret, Christophe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6369410/
https://www.ncbi.nlm.nih.gov/pubmed/30842846
http://dx.doi.org/10.1039/c8sc04868a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6369410/
https://www.ncbi.nlm.nih.gov/pubmed/30842846
http://dx.doi.org/10.1039/c8sc04868a

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