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Enantioselective and site-specific copper-catalyzed reductive allyl–allyl cross-coupling of allenes

A copper-catalyzed asymmetric reductive allyl–allyl cross-coupling reaction of allenes with allylic phosphates wherein allenes were used as allylmetal surrogates has been achieved for the first time. This protocol provides an efficient and straightforward route to optically active 1,5-dienes in a hi...

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Detalles Bibliográficos
Autores principales: Xu, Guoxing, Fu, Bin, Zhao, Haiyan, Li, Yanfei, Zhang, Ge, Wang, Ying, Xiong, Tao, Zhang, Qian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6369434/
https://www.ncbi.nlm.nih.gov/pubmed/30842848
http://dx.doi.org/10.1039/c8sc04505d