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Anion control of tautomeric equilibria: Fe–H vs. N–H influenced by NH···F hydrogen bonding
Counterions can play an active role in chemical reactivity, modulating reaction pathways, energetics and selectivity. We investigated the tautomeric equilibrium resulting from protonation of Fe(P(Et)N(Me)P(Et))(CO)(3) (P(Et)N(Me)P(Et) = (Et(2)PCH(2))(2)NMe) at Fe or N. Protonation of Fe(P(Et)N(Me)P(...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6369578/ https://www.ncbi.nlm.nih.gov/pubmed/30842818 http://dx.doi.org/10.1039/c8sc04239j |