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Anion control of tautomeric equilibria: Fe–H vs. N–H influenced by NH···F hydrogen bonding

Counterions can play an active role in chemical reactivity, modulating reaction pathways, energetics and selectivity. We investigated the tautomeric equilibrium resulting from protonation of Fe(P(Et)N(Me)P(Et))(CO)(3) (P(Et)N(Me)P(Et) = (Et(2)PCH(2))(2)NMe) at Fe or N. Protonation of Fe(P(Et)N(Me)P(...

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Detalles Bibliográficos
Autores principales:	Chambers, Geoffrey M., Johnson, Samantha I., Raugei, Simone, Bullock, R. Morris
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6369578/ https://www.ncbi.nlm.nih.gov/pubmed/30842818 http://dx.doi.org/10.1039/c8sc04239j

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