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The opposite and amplifying effect of B ← N coordination on photophysical properties of regioisomers with an unsymmetrical backbone

1,3-Dipolar cycloaddition of pyrido[2,1-a]isoindole with internal alkynes functionalized by a BMes(2)ph and an N-aromatic heterocycle leads to the formation of two types of regioisomers (major a and minor b) that have distinct physical and photophysical properties. Examination on 5 pairs of regioiso...

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Detalles Bibliográficos
Autores principales: Zeng, Chao, Yuan, Kang, Wang, Nan, Peng, Tai, Wu, Gang, Wang, Suning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6369733/
https://www.ncbi.nlm.nih.gov/pubmed/30842837
http://dx.doi.org/10.1039/c8sc04210a