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A novel and efficient synthesis of phenanthrene derivatives via palladium/norbornadiene-catalyzed domino one-pot reaction

Herein we report a novel palladium-catalyzed reaction that results in phenanthrene derivatives using aryl iodides, ortho-bromobenzoyl chlorides and norbornadiene in one pot. This dramatic transformation undergoes ortho-C–H activation, decarbonylation and subsequent a retro-Diels–Alder process. Pleas...

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Detalles Bibliográficos
Autores principales: Zhong, Yue, Wu, Wen-Yu, Yu, Shao-Peng, Fan, Tian-Yuan, Yu, Hai-Tao, Li, Nian-Guang, Shi, Zhi-Hao, Tang, Yu-Ping, Duan, Jin-Ao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6369988/
https://www.ncbi.nlm.nih.gov/pubmed/30800179
http://dx.doi.org/10.3762/bjoc.15.26