A [4Fe-4S]-Fe(CO)(CN)-L-cysteine intermediate is the first organometallic precursor in [FeFe] hydrogenase H-cluster bioassembly

Biosynthesis of the [FeFe] hydrogenase active site (the “H-cluster”) requires the interplay of multiple proteins and small molecules. Among them, the radical S-adenosyl-methionine enzyme HydG, a tyrosine lyase, has been proposed to generate an Fe(CO)(2)(CN) moiety-containing complex that is eventual...

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Detalles Bibliográficos
Autores principales: Rao, Guodong, Tao, Lizhi, Suess, Daniel L. M., Britt, R. David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6380689/
https://www.ncbi.nlm.nih.gov/pubmed/29632334
http://dx.doi.org/10.1038/s41557-018-0026-7

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6380689/
https://www.ncbi.nlm.nih.gov/pubmed/29632334
http://dx.doi.org/10.1038/s41557-018-0026-7

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