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A [4Fe-4S]-Fe(CO)(CN)-L-cysteine intermediate is the first organometallic precursor in [FeFe] hydrogenase H-cluster bioassembly
Biosynthesis of the [FeFe] hydrogenase active site (the “H-cluster”) requires the interplay of multiple proteins and small molecules. Among them, the radical S-adenosyl-methionine enzyme HydG, a tyrosine lyase, has been proposed to generate an Fe(CO)(2)(CN) moiety-containing complex that is eventual...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6380689/ https://www.ncbi.nlm.nih.gov/pubmed/29632334 http://dx.doi.org/10.1038/s41557-018-0026-7 |