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Stereoselective synthesis of sulfur-containing β-enaminonitrile derivatives through electrochemical Csp(3)–H bond oxidative functionalization of acetonitrile

Incorporation of nitrile groups into fine chemicals is of particular interest through C(sp(3))–H bonds activation of alkyl nitriles in the synthetic chemistry due to the highly efficient atom economy. However, the direct α-functionalization of alkyl nitriles is usually limited to its enolate chemist...

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Detalles Bibliográficos
Autores principales: He, Tian-Jun, Ye, Zongren, Ke, Zhuofeng, Huang, Jing-Mei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6381189/
https://www.ncbi.nlm.nih.gov/pubmed/30783088
http://dx.doi.org/10.1038/s41467-019-08762-5