Hydrogen peroxide as a hydride donor and reductant under biologically relevant conditions

Some ruthenium–hydride complexes react with O(2) to yield H(2)O(2), therefore the principle of microscopic reversibility dictates that the reverse reaction is also possible, that H(2)O(2) could transfer an H(–) to a Ru complex. Mechanistic evidence is presented, using the Ru-catalyzed ABTS˙(–) reduc...

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Detalles Bibliográficos
Autores principales: Htet, Yamin, Lu, Zhuomin, Trauger, Sunia A., Tennyson, Andrew G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6381410/
https://www.ncbi.nlm.nih.gov/pubmed/30881631
http://dx.doi.org/10.1039/c8sc05418e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6381410/
https://www.ncbi.nlm.nih.gov/pubmed/30881631
http://dx.doi.org/10.1039/c8sc05418e

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