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Hydrogen peroxide as a hydride donor and reductant under biologically relevant conditions
Some ruthenium–hydride complexes react with O(2) to yield H(2)O(2), therefore the principle of microscopic reversibility dictates that the reverse reaction is also possible, that H(2)O(2) could transfer an H(–) to a Ru complex. Mechanistic evidence is presented, using the Ru-catalyzed ABTS˙(–) reduc...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6381410/ https://www.ncbi.nlm.nih.gov/pubmed/30881631 http://dx.doi.org/10.1039/c8sc05418e |