New Molybdenum(II) Complexes with α-Diimine Ligands: Synthesis, Structure, and Catalytic Activity in Olefin Epoxidation

Three new complexes [Mo(η(3)-C(3)H(5))Br(CO)(2){(i)PrN=C(R)C(5)H(4)N}], where R = H (IMP = N-isopropyl 2-iminomethylpyridine), Me, and Ph, were synthesized and characterized, and were fluxional in solution. The most interesting feature was the presence, in the crystal structure of the IMP derivative...

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Detalles Bibliográficos
Autores principales: Vasconcellos-Dias, Maria, Marreiros, João, Sales, Rita, Félix, Vitor, Brandão, Paula, Nunes, Carla D., Calhorda, Maria José
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6384641/
https://www.ncbi.nlm.nih.gov/pubmed/30736295
http://dx.doi.org/10.3390/molecules24030578

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6384641/
https://www.ncbi.nlm.nih.gov/pubmed/30736295
http://dx.doi.org/10.3390/molecules24030578

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