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Ring Expansion of Alkylidenecarbenes Derived from Lactams, Lactones, and Thiolactones into Strained Heterocyclic Alkynes: A Theoretical Study

Strained cycloalkynes are of considerable interest to theoreticians and experimentalists, and possess much synthetic value as well. Herein, a series of cyclic alkylidenecarbenes—formally obtained by replacing the carbonyl oxygen of four-, five-, and six-membered lactams, lactones, and thiolactones w...

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Detalles Bibliográficos
Autores principales: Le, Nguyen Nhat Thu, Just, Josefine, Pankauski, Jonathan M., Rablen, Paul R., Thamattoor, Dasan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6384652/
https://www.ncbi.nlm.nih.gov/pubmed/30736417
http://dx.doi.org/10.3390/molecules24030593