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Boron-based stepwise dioxygen activation with 1,4,2,5-diazadiborinine
Activation of dioxygen (O(2)) by 1,4,2,5-diazadiborinine 1 is reported. Two boron centers in 1 undergo a formal [4 + 2] cycloaddition with O(2) at room temperature affording a bicyclo[2.2.2] molecule 2 featuring a B–O–O–B unit. Treatment of 2 with an additional equivalent of 1 leads to the cleavage...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385103/ https://www.ncbi.nlm.nih.gov/pubmed/30881633 http://dx.doi.org/10.1039/c8sc04624g |