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Self- regeneration of Au/CeO(2) based catalysts with enhanced activity and ultra-stability for acetylene hydrochlorination
Replacement of Hg with non-toxic Au based catalysts for industrial hydrochlorination of acetylene to vinyl chloride is urgently required. However Au catalysts suffer from progressive deactivation caused by auto-reduction of Au(I) and Au(III) active sites and irreversible aggregation of Au(0) inactiv...
Autores principales: | , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385229/ https://www.ncbi.nlm.nih.gov/pubmed/30796236 http://dx.doi.org/10.1038/s41467-019-08827-5 |