Characterized cis-Fe(V)(O)(OH) intermediate mimics enzymatic oxidations in the gas phase

Fe(V)(O)(OH) species have long been proposed to play a key role in a wide range of biomimetic and enzymatic oxidations, including as intermediates in arene dihydroxylation catalyzed by Rieske oxygenases. However, the inability to accumulate these intermediates in solution has thus far prevented thei...

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Detalles Bibliográficos
Autores principales: Borrell, Margarida, Andris, Erik, Navrátil, Rafael, Roithová, Jana, Costas, Miquel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385299/
https://www.ncbi.nlm.nih.gov/pubmed/30796210
http://dx.doi.org/10.1038/s41467-019-08668-2

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385299/
https://www.ncbi.nlm.nih.gov/pubmed/30796210
http://dx.doi.org/10.1038/s41467-019-08668-2

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