Cargando…
Characterized cis-Fe(V)(O)(OH) intermediate mimics enzymatic oxidations in the gas phase
Fe(V)(O)(OH) species have long been proposed to play a key role in a wide range of biomimetic and enzymatic oxidations, including as intermediates in arene dihydroxylation catalyzed by Rieske oxygenases. However, the inability to accumulate these intermediates in solution has thus far prevented thei...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2019
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385299/ https://www.ncbi.nlm.nih.gov/pubmed/30796210 http://dx.doi.org/10.1038/s41467-019-08668-2 |