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Cobalt-bridged secondary building units in a titanium metal–organic framework catalyze cascade reduction of N-heteroarenes

We report here a novel Ti(3)–BPDC metal–organic framework (MOF) constructed from biphenyl-4,4′-dicarboxylate (BPDC) linkers and Ti(3)(OH)(2) secondary building units (SBUs) with permanent porosity and large 1D channels. Ti–OH groups from neighboring SBUs point toward each other with an O–O distance...

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Detalles Bibliográficos
Autores principales: Feng, Xuanyu, Song, Yang, Chen, Justin S., Li, Zhe, Chen, Emily Y., Kaufmann, Michael, Wang, Cheng, Lin, Wenbin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385530/
https://www.ncbi.nlm.nih.gov/pubmed/30881644
http://dx.doi.org/10.1039/c8sc04610g