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Experimental observation of nonadiabatic bifurcation dynamics at resonances in the continuum
The surface crossing of bound and unbound electronic states in multidimensional space often gives rise to resonances in the continuum. This situation happens in the πσ*-mediated photodissociation reaction of 2-fluorothioanisole; optically-bright bound S(1) (ππ*) vibrational states of 2-fluorothioani...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385646/ https://www.ncbi.nlm.nih.gov/pubmed/30881669 http://dx.doi.org/10.1039/c8sc04859b |