Halogenoborane mediated allene cyclooligomerization

The halogenoboranes XB(C(6)F(5))(2) (X: Cl, Br) react with allene to give a mixture of the cyclotrimer 1,3,5-trimethylenecyclohexane (1) and the related halogenoborylated cyclotetramerization products 3a and 3b. Alkyl-substituted allenes were catalytically cyclotrimerized metal-free by XB(C(6)F(5))(...

Descripción completa

Detalles Bibliográficos
Autores principales: Tao, Xin, Wölke, Christian, Daniliuc, Constantin G., Kehr, Gerald, Erker, Gerhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385850/
https://www.ncbi.nlm.nih.gov/pubmed/30881677
http://dx.doi.org/10.1039/c8sc04790a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385850/
https://www.ncbi.nlm.nih.gov/pubmed/30881677
http://dx.doi.org/10.1039/c8sc04790a

Ejemplares similares