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Halogenoborane mediated allene cyclooligomerization

The halogenoboranes XB(C(6)F(5))(2) (X: Cl, Br) react with allene to give a mixture of the cyclotrimer 1,3,5-trimethylenecyclohexane (1) and the related halogenoborylated cyclotetramerization products 3a and 3b. Alkyl-substituted allenes were catalytically cyclotrimerized metal-free by XB(C(6)F(5))(...

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Detalles Bibliográficos
Autores principales:	Tao, Xin, Wölke, Christian, Daniliuc, Constantin G., Kehr, Gerald, Erker, Gerhard
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385850/ https://www.ncbi.nlm.nih.gov/pubmed/30881677 http://dx.doi.org/10.1039/c8sc04790a

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