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Enantioselective [1,3] O-to-C rearrangement: dearomatization of alkyl 2-allyloxy/benzyloxy-1/3-naphthoates catalyzed by a chiral π–Cu(ii) complex

An unprecedented catalytic asymmetric [1,3] O-to-C rearrangement of alkyl 2-allyloxy/benzyloxy-1/3-naphthoates was realized under the catalysis of a chiral π–Cu(ii) complex (1–10 mol%). This dearomatization strategy provides facile access to highly functionalized β-naphthalenone derivatives bearing...

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Detalles Bibliográficos
Autores principales: Yao, Lu, Ishihara, Kazuaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6385897/
https://www.ncbi.nlm.nih.gov/pubmed/30881650
http://dx.doi.org/10.1039/c8sc05601c