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Palladium‐Catalyzed C(sp(3))−H Arylation of Primary Amines Using a Catalytic Alkyl Acetal to Form a Transient Directing Group
C−H Functionalization of amines is a prominent challenge due to the strong complexation of amines to transition metal catalysts, and therefore typically requires derivatization at nitrogen with a directing group. Transient directing groups (TDGs) permit C−H functionalization in a single operation, w...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6391947/ https://www.ncbi.nlm.nih.gov/pubmed/30255961 http://dx.doi.org/10.1002/chem.201804515 |