Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework

MFM‐300(Al) shows reversible uptake of NH(3) (15.7 mmol g(−1) at 273 K and 1.0 bar) over 50 cycles with an exceptional packing density of 0.62 g cm(−3) at 293 K. In situ neutron powder diffraction and synchrotron FTIR micro‐spectroscopy on ND(3)@MFM‐300(Al) confirms reversible H/D site exchange betw...

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Detalles Bibliográficos
Autores principales: Godfrey, Harry G. W., da Silva, Ivan, Briggs, Lydia, Carter, Joseph H., Morris, Christopher G., Savage, Mathew, Easun, Timothy L., Manuel, Pascal, Murray, Claire A., Tang, Chiu C., Frogley, Mark D., Cinque, Gianfelice, Yang, Sihai, Schröder, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6391960/
https://www.ncbi.nlm.nih.gov/pubmed/30098090
http://dx.doi.org/10.1002/anie.201808316

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6391960/
https://www.ncbi.nlm.nih.gov/pubmed/30098090
http://dx.doi.org/10.1002/anie.201808316

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