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Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework
MFM‐300(Al) shows reversible uptake of NH(3) (15.7 mmol g(−1) at 273 K and 1.0 bar) over 50 cycles with an exceptional packing density of 0.62 g cm(−3) at 293 K. In situ neutron powder diffraction and synchrotron FTIR micro‐spectroscopy on ND(3)@MFM‐300(Al) confirms reversible H/D site exchange betw...
| Autores principales: | , , , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6391960/ https://www.ncbi.nlm.nih.gov/pubmed/30098090 http://dx.doi.org/10.1002/anie.201808316 |
| _version_ | 1783398399824887808 |
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| author | Godfrey, Harry G. W. da Silva, Ivan Briggs, Lydia Carter, Joseph H. Morris, Christopher G. Savage, Mathew Easun, Timothy L. Manuel, Pascal Murray, Claire A. Tang, Chiu C. Frogley, Mark D. Cinque, Gianfelice Yang, Sihai Schröder, Martin |
| author_facet | Godfrey, Harry G. W. da Silva, Ivan Briggs, Lydia Carter, Joseph H. Morris, Christopher G. Savage, Mathew Easun, Timothy L. Manuel, Pascal Murray, Claire A. Tang, Chiu C. Frogley, Mark D. Cinque, Gianfelice Yang, Sihai Schröder, Martin |
| author_sort | Godfrey, Harry G. W. |
| collection | PubMed |
| description | MFM‐300(Al) shows reversible uptake of NH(3) (15.7 mmol g(−1) at 273 K and 1.0 bar) over 50 cycles with an exceptional packing density of 0.62 g cm(−3) at 293 K. In situ neutron powder diffraction and synchrotron FTIR micro‐spectroscopy on ND(3)@MFM‐300(Al) confirms reversible H/D site exchange between the adsorbent and adsorbate, representing a new type of adsorption interaction. |
| format | Online Article Text |
| id | pubmed-6391960 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2018 |
| publisher | John Wiley and Sons Inc. |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-63919602019-03-07 Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework Godfrey, Harry G. W. da Silva, Ivan Briggs, Lydia Carter, Joseph H. Morris, Christopher G. Savage, Mathew Easun, Timothy L. Manuel, Pascal Murray, Claire A. Tang, Chiu C. Frogley, Mark D. Cinque, Gianfelice Yang, Sihai Schröder, Martin Angew Chem Int Ed Engl Communications MFM‐300(Al) shows reversible uptake of NH(3) (15.7 mmol g(−1) at 273 K and 1.0 bar) over 50 cycles with an exceptional packing density of 0.62 g cm(−3) at 293 K. In situ neutron powder diffraction and synchrotron FTIR micro‐spectroscopy on ND(3)@MFM‐300(Al) confirms reversible H/D site exchange between the adsorbent and adsorbate, representing a new type of adsorption interaction. John Wiley and Sons Inc. 2018-10-01 2018-11-05 /pmc/articles/PMC6391960/ /pubmed/30098090 http://dx.doi.org/10.1002/anie.201808316 Text en © 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
| spellingShingle | Communications Godfrey, Harry G. W. da Silva, Ivan Briggs, Lydia Carter, Joseph H. Morris, Christopher G. Savage, Mathew Easun, Timothy L. Manuel, Pascal Murray, Claire A. Tang, Chiu C. Frogley, Mark D. Cinque, Gianfelice Yang, Sihai Schröder, Martin Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework |
| title | Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework |
| title_full | Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework |
| title_fullStr | Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework |
| title_full_unstemmed | Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework |
| title_short | Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework |
| title_sort | ammonia storage by reversible host–guest site exchange in a robust metal–organic framework |
| topic | Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6391960/ https://www.ncbi.nlm.nih.gov/pubmed/30098090 http://dx.doi.org/10.1002/anie.201808316 |
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