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Lateral Adsorbate Interactions Inhibit HCOO(−) while Promoting CO Selectivity for CO(2) Electrocatalysis on Silver

Ag is a promising catalyst for the production of carbon monoxide (CO) via the electrochemical reduction of carbon dioxide (CO(2)ER). Herein, we study the role of the formate (HCOO(−)) intermediate *OCHO, aiming to resolve the discrepancy between the theoretical understanding and experimental perform...

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Detalles Bibliográficos
Autores principales: Bohra, Divya, Ledezma‐Yanez, Isis, Li, Guanna, de Jong, Wiebren, Pidko, Evgeny A., Smith, Wilson A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6391976/
https://www.ncbi.nlm.nih.gov/pubmed/30444950
http://dx.doi.org/10.1002/anie.201811667