Cargando…
A convenient method for the generation of {Rh(PNP)}(+) and {Rh(PONOP)}(+) fragments: reversible formation of vinylidene derivatives
The substitution reactions of [Rh(COD)(2)][BAr(F)(4)] with PNP and PONOP pincer ligands 2,6-bis(di-tert-butylphosphinomethyl)pyridine and 2,6-bis(di-tert-butylphosphinito)pyridine in the weakly coordinating solvent 1,2-F(2)C(6)H(4) are shown to be an operationally simple method for the generation of...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6394201/ https://www.ncbi.nlm.nih.gov/pubmed/30729961 http://dx.doi.org/10.1039/c8dt05049j |