Cargando…

A convenient method for the generation of {Rh(PNP)}(+) and {Rh(PONOP)}(+) fragments: reversible formation of vinylidene derivatives

The substitution reactions of [Rh(COD)(2)][BAr(F)(4)] with PNP and PONOP pincer ligands 2,6-bis(di-tert-butylphosphinomethyl)pyridine and 2,6-bis(di-tert-butylphosphinito)pyridine in the weakly coordinating solvent 1,2-F(2)C(6)H(4) are shown to be an operationally simple method for the generation of...

Descripción completa

Detalles Bibliográficos
Autores principales: Gyton, Matthew R., Hood, Thomas M., Chaplin, Adrian B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6394201/
https://www.ncbi.nlm.nih.gov/pubmed/30729961
http://dx.doi.org/10.1039/c8dt05049j