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A convenient method for the generation of {Rh(PNP)}(+) and {Rh(PONOP)}(+) fragments: reversible formation of vinylidene derivatives

The substitution reactions of [Rh(COD)(2)][BAr(F)(4)] with PNP and PONOP pincer ligands 2,6-bis(di-tert-butylphosphinomethyl)pyridine and 2,6-bis(di-tert-butylphosphinito)pyridine in the weakly coordinating solvent 1,2-F(2)C(6)H(4) are shown to be an operationally simple method for the generation of...

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Detalles Bibliográficos
Autores principales:	Gyton, Matthew R., Hood, Thomas M., Chaplin, Adrian B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6394201/ https://www.ncbi.nlm.nih.gov/pubmed/30729961 http://dx.doi.org/10.1039/c8dt05049j

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