Base-Promoted, Remote C–H Activation at a Cationic (η(5)-C(5)Me(5))Ir(III) Center Involving Reversible C–C Bond Formation of Bound C(5)Me(5)

[Image: see text] C–H bond activation at cationic [(η(5)-C(5)Me(5))Ir(PMe(2)Ar′)] centers is described, where PMe(2)Ar′ are the terphenyl phosphine ligands PMe(2)Ar(Xyl)(2) and PMe(2)Ar(Dipp)(2). Different pathways are defined for the conversion of the five-coordinate complexes [(η(5)-C(5)Me(5))IrCl...

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Detalles Bibliográficos
Autores principales: Moreno, Juan J., Espada, María F., Campos, Jesús, López-Serrano, Joaquín, Macgregor, Stuart A., Carmona, Ernesto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6396953/
https://www.ncbi.nlm.nih.gov/pubmed/30682245
http://dx.doi.org/10.1021/jacs.8b11752

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6396953/
https://www.ncbi.nlm.nih.gov/pubmed/30682245
http://dx.doi.org/10.1021/jacs.8b11752

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