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Crystal structure of [1,3-bis­(2,4,6-tri­methyl­phen­yl)imidazolidin-2-yl­idene]di­chlorido­{2-[1-(di­methyl­amino)­eth­yl]benzyl­idene}ruthenium including an unknown solvate

The title compound, [RuCl(2)(C(21)H(26)N(2))(C(11)H(15)N)], is an example of a new generation of N,N-dialkyl metallocomplex ruthenium catalysts with an N→Ru coordination bond as part of a six-membered chelate ring. The Ru atom has an Addison τ parameter of 0.234, which indicates a geometry inter­med...

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Detalles Bibliográficos
Autores principales: Polyanskii, Kirill B., Alekseeva, Kseniia A., Kumandin, Pavel A., Atioğlu, Zeliha, Akkurt, Mehmet, Toze, Flavien A. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6399687/
https://www.ncbi.nlm.nih.gov/pubmed/30867945
http://dx.doi.org/10.1107/S2056989019001725