Proposed Mechanism for the High-Yield Polymerization of Oxyethyl Propiolates with Rh Complex Catalyst Using the Density Functional Theory Method

In this study, poly(oxyethyl propiolate)s (POP)s featuring various oxyethylene derivatives are synthesized using a [Rh(norbornadiene)Cl](2) catalyst. In particular, POPs featuring the normal oxyethylene chain in the side-chain exhibit excellent yields and high molecular weights in methanol and N,N-d...

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Detalles Bibliográficos
Autores principales: Yoshida, Yoshiaki, Mawatari, Yasuteru, Tabata, Masayoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6402018/
https://www.ncbi.nlm.nih.gov/pubmed/30960077
http://dx.doi.org/10.3390/polym11010093

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6402018/
https://www.ncbi.nlm.nih.gov/pubmed/30960077
http://dx.doi.org/10.3390/polym11010093

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