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Substituent Effects of Phenyl Group on Silylene Bridge in Stereospecific Polymerization of Propylene with C(1)-Symmetric Ansa-Silylene(fluorenyl)(amido) Dimethyl Titanium Complexes
A C(1)-symmetric (methylphenyl)silylene-bridged (fluorenyl)(naphthylamido) titanium complex (1) and (diphenyl)silylene-bridged (fluorenyl)(naphthylamido) titanium complex (2) were synthesized and characterized by (1)H NMR, element analysis, and X-ray crystal analysis. The coordination mode of the fl...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6403971/ https://www.ncbi.nlm.nih.gov/pubmed/30961000 http://dx.doi.org/10.3390/polym10101075 |