Ring-Expansion/Contraction Radical Crossover Reactions of Cyclic Alkoxyamines: A Mechanism for Ring Expansion-Controlled Radical Polymerization

Macrocyclic polymers present an important class of macromolecules, displaying the reduced radius of gyration or impossibility to entangle. A rare approach for their synthesis is the ring expansion-controlled radical “vinyl” polymerization, starting from a cyclic alkoxyamine. We here describe ring-ex...

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Detalles Bibliográficos
Autores principales: Narumi, Atsushi, Kobayashi, Tetsuya, Yamada, Masatsugu, Binder, Wolfgang H., Matsuda, Keigo, Shaykoon, Montaser Shaykoon Ahmed, Enomoto, Kazushi, Kikuchi, Moriya, Kawaguchi, Seigou
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6404036/
https://www.ncbi.nlm.nih.gov/pubmed/30966672
http://dx.doi.org/10.3390/polym10060638

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6404036/
https://www.ncbi.nlm.nih.gov/pubmed/30966672
http://dx.doi.org/10.3390/polym10060638

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