Intramolecular cascade annulation triggered by rhodium(III)-catalyzed sequential C(sp(2))–H activation and C(sp(3))–H amination

A rhodium(III)-catalyzed intramolecular oxidative annulation of O-substituted N-hydroxyacrylamides for the construction of indolizinones via sequential C(sp(2))–H activation and C(sp(3))–H amination has been developed. This approach shows excellent functional-group tolerance. The synthesized scaffol...

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Detalles Bibliográficos
Autores principales: Song, Liangliang, Tian, Guilong, Van der Eycken, Johan, Van der Eycken, Erik V
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6404421/
https://www.ncbi.nlm.nih.gov/pubmed/30873242
http://dx.doi.org/10.3762/bjoc.15.52

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6404421/
https://www.ncbi.nlm.nih.gov/pubmed/30873242
http://dx.doi.org/10.3762/bjoc.15.52

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