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Intramolecular cascade annulation triggered by rhodium(III)-catalyzed sequential C(sp(2))–H activation and C(sp(3))–H amination
A rhodium(III)-catalyzed intramolecular oxidative annulation of O-substituted N-hydroxyacrylamides for the construction of indolizinones via sequential C(sp(2))–H activation and C(sp(3))–H amination has been developed. This approach shows excellent functional-group tolerance. The synthesized scaffol...
Autores principales: | Song, Liangliang, Tian, Guilong, Van der Eycken, Johan, Van der Eycken, Erik V |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6404421/ https://www.ncbi.nlm.nih.gov/pubmed/30873242 http://dx.doi.org/10.3762/bjoc.15.52 |
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