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Conformational signature of Ishikawa´s reagent using NMR information from diastereotopic fluorines

The active species of the Ishikawa´s reagent [N,N-diethyl-(1,1,2,3,3,3-hexafluoropropyl)amine] is a fluorinating hexafluoropropylamine used to convert alcohols into alkyl fluorides. On the other hand, it is also an example of model compound useful to probe conformational preferences using spectrosco...

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Detalles Bibliográficos
Autores principales: Andrade, Laize A F, Zeoly, Lucas A, Cormanich, Rodrigo A, Freitas, Matheus P
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6404478/
https://www.ncbi.nlm.nih.gov/pubmed/30873234
http://dx.doi.org/10.3762/bjoc.15.44