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Titanium(IV)-induced cristobalite formation in titanosilicates and its potential impact on catalysis

Cristobalite, a crystalline form of silica, is shown to be formed within an amorphous titanosilicate, at previously unknown conditions. Mesoporous titanosilicate microspheres (MTSM) were synthesized as efficient catalysts for the epoxidation of cyclohexene with tert-butyl hydroperoxide. High-resolut...

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Detalles Bibliográficos
Autores principales: Perera, Ayomi S., Cockcroft, Jeremy K., Trogadas, Panagiotis, Yu, Haiyue, Kapil, Nidhi, Coppens, Marc-Olivier
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6411274/
https://www.ncbi.nlm.nih.gov/pubmed/30930477
http://dx.doi.org/10.1007/s10853-018-2869-0