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Thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers

There is often a trade-off between mechanical properties (modulus and toughness) and dynamic self-healing. Here we report the design and synthesis of a polymer containing thermodynamically stable whilst kinetically labile coordination complex to address this conundrum. The Zn-Hbimcp (Hbimcp = 2,6-bi...

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Detalles Bibliográficos
Autores principales: Lai, Jian-Cheng, Jia, Xiao-Yong, Wang, Da-Peng, Deng, Yi-Bing, Zheng, Peng, Li, Cheng-Hui, Zuo, Jing-Lin, Bao, Zhenan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6411951/
https://www.ncbi.nlm.nih.gov/pubmed/30858371
http://dx.doi.org/10.1038/s41467-019-09130-z