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Thermodynamically stable whilst kinetically labile coordination bonds lead to strong and tough self-healing polymers
There is often a trade-off between mechanical properties (modulus and toughness) and dynamic self-healing. Here we report the design and synthesis of a polymer containing thermodynamically stable whilst kinetically labile coordination complex to address this conundrum. The Zn-Hbimcp (Hbimcp = 2,6-bi...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6411951/ https://www.ncbi.nlm.nih.gov/pubmed/30858371 http://dx.doi.org/10.1038/s41467-019-09130-z |