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Design and Synthesis of a Novel Banana-Shaped Functional Molecule via Double Cross-Coupling

A novel banana-shaped molecule using 2,8-Dimethyl-6H,12H-5,11-methanodibenzo [b,f] [1,5]diazocine (Tröger’s base) as bent-core was synthesized via double Carbon-Carbon cross-coupling reaction. The double Sonogashira cross-coupling reaction was optimized by using Pd(PPh(3))(2)Cl(2) as catalyst, CuI a...

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Detalles Bibliográficos
Autores principales: Yang, Bingchuan, Shen, Guodong, Huang, Xianqiang, Liu, Rutao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6412220/
https://www.ncbi.nlm.nih.gov/pubmed/30769955
http://dx.doi.org/10.3390/molecules24040698