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Titanium(III, IV)-Containing Catalytic Systems for Production of Ultrahigh Molecular Weight Polyethylene Nascent Reactor Powders, Suitable for Solventless Processing—Impact of Oxidation States of Transition Metal

Catalytic systems containing TiCl(4) or TiCl(3), THF, organomagnesium (n-Bu(2)Mg) and organoaluminum compounds capable of producing ultrahigh molecular weight polyethylene (UHMWPE) were developed. The resulting polymers were characterized by a molecular weight in the range of (1.8–7.8) × 10(6) Da an...

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Detalles Bibliográficos
Autores principales: Tuskaev, Vladislav A., Gagieva, Svetlana C., Kurmaev, Dmitrii A., Kolosov, Nikolay A., Mikhaylik, Elena S., Golubev, Evgenii K., Sizov, Alexander I., Zubkevich, Sergey V., Vasil’ev, Viktor G., Nikiforova, Galina G., Buzin, Mikhail I., Serenko, Olga A., Bulychev, Boris M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6414873/
https://www.ncbi.nlm.nih.gov/pubmed/30966039
http://dx.doi.org/10.3390/polym10010002