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Two New Three-Dimensional Pillared-Layer Co(II) and Cu(II) Frameworks Involving a [M(2)(EO-N(3))(2)] Motif from a Semi-Flexible N-Donor Ligand, 5,5′-Bipyrimidin: Syntheses, Structures and Magnetic Properties

Two new three-dimensional (3D) Co(II)- and Cu(II)-azido frameworks, [Co(2)(N(3))(4)(bpym)(2)](n) (1) and [Cu(2)(N(3))(4)(bpym)](n) (2), were successfully synthesized by introducing a semi-flexible N-donor ligand, 5,5′-bipyrimidin (bpym), with different bridging modes and orientations. Compounds 1 an...

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Detalles Bibliográficos
Autores principales: Zhang, Zu-Zhen, Chang, Han-Ting, Kuo, Yi Lin, Lee, Gene-Hsiang, Yang, Chen-I
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6415140/
https://www.ncbi.nlm.nih.gov/pubmed/30966264
http://dx.doi.org/10.3390/polym10030229