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Two New Three-Dimensional Pillared-Layer Co(II) and Cu(II) Frameworks Involving a [M(2)(EO-N(3))(2)] Motif from a Semi-Flexible N-Donor Ligand, 5,5′-Bipyrimidin: Syntheses, Structures and Magnetic Properties
Two new three-dimensional (3D) Co(II)- and Cu(II)-azido frameworks, [Co(2)(N(3))(4)(bpym)(2)](n) (1) and [Cu(2)(N(3))(4)(bpym)](n) (2), were successfully synthesized by introducing a semi-flexible N-donor ligand, 5,5′-bipyrimidin (bpym), with different bridging modes and orientations. Compounds 1 an...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6415140/ https://www.ncbi.nlm.nih.gov/pubmed/30966264 http://dx.doi.org/10.3390/polym10030229 |