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Ammonothermal Synthesis, X‐Ray and Time‐of‐Flight Neutron Crystal‐Structure Determination, and Vibrational Properties of Barium Guanidinate, Ba(CN(3)H(4))(2)

We report the crystal structure of Ba(CN(3)H(4))(2) as synthesized from liquid ammonia. Structure solution based on X‐ray diffraction data suffers from a severe pseudo‐tetragonal problem due to extreme scattering contrast, so the true monoclinic symmetry is detectable only from neutron powder diffra...

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Detalles Bibliográficos
Autores principales: Benz, Sebastian, Missong, Ronja, Ogutu, George, Stoffel, Ralf P., Englert, Ulli, Torii, Shuki, Miao, Ping, Kamiyama, Takashi, Dronskowski, Richard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6417364/
https://www.ncbi.nlm.nih.gov/pubmed/30915268
http://dx.doi.org/10.1002/open.201900068