Helix-Sense-Selective Polymerization of Phenylacetylenes Having a Porphyrin and a Zinc-Porphyrin Group: One-Handed Helical Arrangement of Porphyrin Pendants

Newly synthesized two kinds of achiral phenylacetylenes having a free-base- or a zinc-porphyrin (1 and Zn1, respectively) were polymerized by using a chiral rhodium catalyst system, Rh(+)(nbd)[(η(6)-C(6)H(5))B(–)(C(6)H(5))(3)] catalyst and (R)-(+)- or (S)-(–)-1-phenylethylamine ((R)- or (S)-PEA, res...

Descripción completa

Detalles Bibliográficos
Autores principales: Teraguchi, Masahiro, Nahata, Nobuyuki, Nishimura, Takahiro, Aoki, Toshiki, Kaneko, Takashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419054/
https://www.ncbi.nlm.nih.gov/pubmed/30960258
http://dx.doi.org/10.3390/polym11020274

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419054/
https://www.ncbi.nlm.nih.gov/pubmed/30960258
http://dx.doi.org/10.3390/polym11020274

Ejemplares similares