Investigations on non-classical silylium ions leading to a cyclobutenyl cation

Instead of yielding the desired non-classical silylium ions, the reactions of different alkenes/alkynes with several [Me(3)Si](+) sources mostly led to oligomerization, or – in the presence of Me(3)SiH – hydrosilylation of the alkenes/alkynes. Yet, from the reaction of 2-butyne with ion-like Me(3)Si...

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Detalles Bibliográficos
Autores principales: Martens, Arthur, Kreuzer, Marvin, Ripp, Alexander, Schneider, Marius, Himmel, Daniel, Scherer, Harald, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419934/
https://www.ncbi.nlm.nih.gov/pubmed/30997003
http://dx.doi.org/10.1039/c8sc04591g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419934/
https://www.ncbi.nlm.nih.gov/pubmed/30997003
http://dx.doi.org/10.1039/c8sc04591g

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