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Investigations on non-classical silylium ions leading to a cyclobutenyl cation

Instead of yielding the desired non-classical silylium ions, the reactions of different alkenes/alkynes with several [Me(3)Si](+) sources mostly led to oligomerization, or – in the presence of Me(3)SiH – hydrosilylation of the alkenes/alkynes. Yet, from the reaction of 2-butyne with ion-like Me(3)Si...

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Detalles Bibliográficos
Autores principales:	Martens, Arthur, Kreuzer, Marvin, Ripp, Alexander, Schneider, Marius, Himmel, Daniel, Scherer, Harald, Krossing, Ingo
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419934/ https://www.ncbi.nlm.nih.gov/pubmed/30997003 http://dx.doi.org/10.1039/c8sc04591g

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